Exchange 2010 Outgoing BCC Transport Rule

You can set a Transport Rule for that. Go into EMC, >Orginazation Configuration >Hub Transport. >Create New Transport Rule.

Choose “from people” choose the person you want to copy mail from, click the next button. Find “Blind carbon copy (Bcc) the messate to address and choose the address you want to BCC to, then setup the rest as you wish.